Lecture 38
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Sources of Ground-Water
Contamination
Fetter 11
(I) Sources Designed to discharge substances
| Septic Tanks / Cesspools |
Transform nitrogen to less hazardous forms, do not remove N.
| Injection Wells |
Brine, Hazardous Waste
| Land application |
Sludge- heavy metals, dioxins
(II) Source Designed to Store, Treat, Dispose
| Landfill ® Regulated ~ 12,000 in U.S ~ 2,500 open dumps Leachate generated |
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| Surface Impoundments Pits, Lagoons ® evaporate |
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| Mine Wastes Often inorganic |
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| Animal Burials Radioactive carcasses and other radioactive tracers |
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| Storage Tanks Above / Below ground ® 2.5 million in U.S |
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| Radioactive Waste
Disposal Yucca Mountain |
(III) Retain substances during Transport
| Pipeline-Bemidji | |
| Transfer stations. |
(IV) Discharge as Result of other Activities
| Irrigation Selenium, salts |
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| Pesticides | |
| Fertilizer - natural/ anthropogenic |
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| Road Salt | |
| Urban Runoff | |
| Water Softeners |
(V) Sources as conduits to aquifers
| Production wells Poor construction can cause introduction of contaminants. |
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| Excavation |
(VI) Naturally Occurring that is aided by Humans
Saltwater intrusions aided by ground-water withdrawals
Coal mines
Threats to Water Quality
| Perceived | Frequency |
| Nitrates | Underground storage tanks |
| Pesticides | Septic tanks |
| Volatile organic compounds | Agricultural Activity |
| Petroleum products | Landfills |
* Uranium from All Department of Education sites are long-term contamination.
Water Quality Standards
-Regulations on limits of constituents in water.
Safe Drinking Water Act - and amendments passed by Congress
Environment Protection
Agency - Regulatory Agency
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| MCL- Maximum contaminant level (enforced) | |||||||
| MCLG - goals (guidelines
for MCL) Selection criteria include:
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| We are not a zero tolerance society. |
Risk 1 death per 1,000,000
Cancer - assume - lifetime Health Advisory level
Person weighs 70 kilograms and drinking 2 liters of water per day.
| No observable adverse effect level for most sensitive species |
X |
Uncertainty factors 1/100 |
X |
Extra factor 1/10 |
X |
Alternative source factor 1/5 |
= |
Estimated safe human dose in drkinking water (mg/kg/d) |
* feed to rats to see if toxic
Total Dissolved Solids-
-Total amount of solids (mg/L) that remain in a sample that is evaporated to dryness.
| Classification | Total Dissolved Solids(mg/L) |
| Fresh | 1 - 1,000 |
| Blackish | 1,000 - 10,000 |
| Saline | 10,000 - 100,000 |
| Brine | > 100,000 |
Contaminant - makes unfit for use through contact or addition.
Pollute - complete decay through contamination.
-Many types of contaminants occur naturally, many do not.
-Many contaminants can not be tasted.-Radon, As, Cu.
Major Constituents in water are:
Calcium, Magnesium, Sodium, Potassium, Chloride, Sulfide, Carbonate
Bicarbonate, Silicate.
Trace elements- a few mg/L
Dissolved gases- Oxygen, carbondioxide, nitrogen, methane
Important in surface water.
| Microbiological constituents | parasite giardia |
| Bacteria | E. coli |
| Protazoa | Cryptospirdium |