Lecture 38

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Sources of Ground-Water

Contamination

Fetter 11

 

(I) Sources Designed to discharge substances

Septic Tanks / Cesspools

        Transform nitrogen to less hazardous forms, do not remove N.

Injection Wells

        Brine, Hazardous Waste

Land application

       Sludge- heavy metals, dioxins

 

(II) Source Designed to Store, Treat, Dispose

Landfill ® Regulated

~ 12,000 in U.S

~ 2,500 open dumps

Leachate generated

Surface Impoundments

Pits, Lagoons ® evaporate

Mine Wastes

Often inorganic

Animal Burials

Radioactive carcasses and other radioactive tracers

Storage Tanks

Above / Below ground ® 2.5 million in U.S

Radioactive Waste Disposal

Yucca Mountain

 

(III) Retain substances during Transport

Pipeline-Bemidji
Transfer stations.

 

(IV) Discharge as Result of other Activities

Irrigation

Selenium, salts

Pesticides
Fertilizer -

natural/ anthropogenic

Road Salt
Urban Runoff
Water Softeners

 

(V) Sources as conduits to aquifers

Production wells

Poor construction can cause introduction of contaminants.

Excavation

 

(VI) Naturally Occurring that is aided by Humans

 

Saltwater intrusions aided by ground-water withdrawals

 

Coal mines

 

 

Threats to Water Quality

Perceived Frequency
Nitrates Underground storage tanks
Pesticides Septic tanks
Volatile organic compounds Agricultural Activity
Petroleum products Landfills

 

* Uranium from All Department of Education sites are long-term contamination.

 

 

 

Water Quality Standards

 

-Regulations on limits of constituents in water.

 

Safe Drinking Water Act - and amendments passed by Congress

Environment Protection Agency - Regulatory Agency
- developed drinking water standards
MCL- Maximum contaminant level (enforced)
MCLG - goals (guidelines for MCL)

Selection criteria include:

(1) Detection
(2) Potential health risk
(3) Occurrence or potential for occurrence
We are not a zero tolerance society.

 

Risk 1 death per 1,000,000

 

Cancer - assume - lifetime Health Advisory level

 

Person weighs 70 kilograms and drinking 2 liters of water per day.

 

 

No observable adverse effect level for most sensitive species  

 

 

X

 

 

Uncertainty factors 1/100

 

 

 

X

 

 

Extra factor 1/10

 

 

 

X

 

Alternative source factor 1/5

 

 

 

=

Estimated safe human dose in drkinking water (mg/kg/d)

 

* feed to rats to see if toxic

 

 

Total Dissolved Solids-

 

-Total amount of solids (mg/L) that remain in a sample that is evaporated to dryness.

 

Classification Total Dissolved Solids(mg/L)
Fresh 1 - 1,000
Blackish 1,000 - 10,000
Saline 10,000 - 100,000
Brine > 100,000

 

Contaminant - makes unfit for use through contact or addition.

 

Pollute - complete decay through contamination.

 

-Many types of contaminants occur naturally, many do not.

 

-Many contaminants can not be tasted.-Radon, As, Cu.

 

Major Constituents in water are:

Calcium, Magnesium, Sodium, Potassium, Chloride, Sulfide, Carbonate

 

Bicarbonate, Silicate.

 

Trace elements- a few mg/L

 

Dissolved gases- Oxygen, carbondioxide, nitrogen, methane

 

Important in surface water.

 

Microbiological constituents parasite giardia
Bacteria E. coli
Protazoa Cryptospirdium

 

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