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Environmental
Chemistry

Homework
Assignment 5 (20 points)
- Calculate the pressure of oxygen for a system in equilibrium in which [NH4+]
= [NO3-1] at pH = 7.00.
- What is the pE value at the point on the Fe2+/Fe(OH)3 boundary line in a solution with
a soluble iron concentration of 1.00 x 10-4 M at a pH of 6.00?
- What is the pE value in
an acid mine water sample having [Fe3+] = 7.03 x 10-3 M and [Fe2+] = 3.71 x 10-4 M?
- At pH 6.00 and
pE 2.58, what is the concentration of Fe2+ in equilibrium
with Fe(OH)3?
- What is the calculated
value of the partial pressure of O2 in acid mine water of
pH 2.00, in which [Fe3+] =[Fe2+]?

ENV 440 Homework
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